Published in
Elsevier, Studies in Surface Science and Catalysis, p. 329-332
DOI: 10.1016/s0167-2991(10)75053-9
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A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity
,
M. Devillers,
Ilke Muylaert,
Veronique Van Speybroeck ,
S. Hermans,
Pa Jacobs,
Guy B. Marin,
Ja Martens,
Pascal Van Der Voort,
P. Ruiz
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Abstract
A completely saturated Metal Organic Framework, MIL-47 was synthesized and tested for its catalytic performance in the oxidation of cyclohexene with tert-butyl hydroperoxide as oxidant. The catalyst was compared to several reference catalysts: namely VAPO-5, supported VOx/SiO2 and the homogeneous catalyst VO(acac)(2). MIL-47 shows a remarkable catalytic activity and preserves its crystalline structure and surface area after a catalytic run. Furthermore MIL-47 exhibits a very high activity in successive runs.