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Published in

Wiley, European Journal of Lipid Science and Technology, 1(113), p. 59-71, 2010

DOI: 10.1002/ejlt.201000122

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Poly(2-oxazoline)s based on fatty acids

Journal article published in 2010 by Richard Hoogenboom ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Poly(2-oxazoline)s are an interesting class of synthetic poly(amide) s that can be prepared by living cationic ring-opening polymerization. The properties of poly(2-oxazoline) s can be tuned by variation of the 2-substituent of the 2-oxazoline monomer. In this contribution the utilization of fatty acids as side chains for poly(2-oxazoline) s is highlighted. The incorporation of such long aliphatic side-chains results in hydrophobic crystalline poly(2-oxazoline) s that are often applied for the preparation of amphiphilic structures as well as for low surface energy and low adhesive coatings. The most popular fatty-acid based poly(2-oxazoline) s are the saturated poly(2-nonyl-2-oxazoline) and poly(2-undecyl-2-oxazoline) as well as the unsaturated poly(2-decenyl-2-oxazoline) and poly(2-"soy alkyl''-2-oxazoline).