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Elsevier, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 11(60), p. 2511-2516, 2004

DOI: 10.1016/j.saa.2003.12.044

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Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene

Journal article published in 2004 by Y.-U. N. Panchenko, G. R. De Maré, A. V. Abramenkov, M. S. Baird ORCID, V. V. Tverezovsky, A. V. Nizovtsev, I. G. Bolesov
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This paper is available in a repository.

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Abstract

The effects of substitution of X = C by Si or Ge in X(CH3) 3 moieties attached to the formal double bond of 3,3- dimethylcyclopropene are examined. Regularities in observed trends of vibrational frequencies implicating the moieties containing the X atom, as the X atomic mass is increased, are extrapolated to X = Sn. The results of this extrapolation made it possible to assign the known experimental vibrational frequencies of 3,3-dimethyl-1-(trimethylstannyl)cyclopropene and 3,3-dimethyl-1,2-bis(trimethylstannyl)cyclopropene. © 2004 Elsevier B.V. All rights reserved. ; SCOPUS: ar.j ; info:eu-repo/semantics/published