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Effects of lanthanum modification on dielectric properties of Pb(Zr0.90,Ti0.10)O3 ceramics: enhanced antiferroelectric stability

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) ; Processo FAPESP: 06/60013-5 ; Lanthanum modified lead zirconate titanate ceramics with lanthanum content changing from 2 to 6 at% La and a Zr/Ti ratio of 90/10 (PLZT x/90/10) have been analyzed by using X-ray diffraction, dielectric response, differential scanning calorimetry, and ferroelectric hysteresis. An antiferroelectric state was found to be stabilized, whereas the long-range ferroelectric state was disrupted by lanthanum substitution on the lead sites. A ferroelectric state is shown to be stable over an antiferroelectric state for low lanthanum contents in a wide temperature range, where both phases coexist. With the increase of the lanthanum concentration, the long-range coherency of the ferroelectric state is suppressed, i.e., the temperature range of the ferroelectric state stability decreased, disappearing for x > 3 at% La.