This paper reports a simplified one-step hydrothermal approach to prepare the graphene-SnO2-amorphous carbon (Gr-SnO2-C) composites which have a fixed SnO2 content and various graphene to amorphous carbon (Gr/C) mass ratio as anode for Li-ion batteries. The Gr-SnO2-C with a Gr/C mass ratio of 1:4 shows the best cycling stability at a current density of 300 mA g–1. Then, at a low current density of 50 mA g–1, it reveals a reversible capacity of around 878 mAh g–1 after 50 cycles. By studying the microstructure evolution and electrochemical performance as a function of the Gr/C mass ratio, it is discovered that the Gr/C mass ratio can affect the Gr-SnO2-C composites in the aspects of porous structures, conductivity of active materials and microstructural stability. The enhanced performance of the Gr-SnO2-C composites is attributed to the synergism between the graphene, amophous carbon and SnO2 nanoparticles.