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Wiley, Angewandte Chemie International Edition, 45(45), p. 7550-7553, 2006

DOI: 10.1002/anie.200603547

Wiley, Angewandte Chemie, 45(118), p. 7712-7715, 2006

DOI: 10.1002/ange.200603547

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Structure of a Discrete Dichloride Hexahydrate Cube as a Tris(diisopropylamino)cyclopropenium Salt

Journal article published in 2006 by James R. Butchard, David J. Garrett, Robert G. A. R. Maclagan, Owen J. Curnow ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Overcoming repulsion: Two chloride anions are glued together by six Cl⋯H-O hydrogen bonds in the stable dichloride hydrate cube [Cl 2(H2O)6]2-. The solid-state structure of the cluster determined by X-ray diffraction of its salt (see picture; Cl green, O red, H white) is consistent with the gas-phase structures calculated at two levels of theory. (Figure Presented)