Published in

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1-2(301), p. 1-13

DOI: 10.1016/0022-0728(91)85455-x

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Digital simulation via the hopscotch algorithm of a microelectrode-based channel flow-through amperometric detector

Journal article published in 1991 by P. Pastore, F. Magno, I. Lavagnini, C. A. Amatore ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The current flowing at a band ultramicroelectrode in a rectangular channel under mass transfer-limited conditions is computed numerically. The procedure is based on the "hopscotch" algorithm and on an appropriate space transformation, delta = tanh(x/alpha). The edge effect is found to influence the response depending on the flow rate. The polarization times necessary to reach the steady-state current are also computed under different operating conditions.