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American Chemical Society, Nano Letters, 8(8), p. 2541-2546, 2008

DOI: 10.1021/nl8016626

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Programmable Hierarchical Three-Component 2D Assembly at a Liquid-Solid Interface: Recognition, Selection, and Transformation

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Recognition and selection are of fundamental importance for the hierarchical assembly of supramolecular systems. Coronene induces the formation of a hydrogen-bonded isophthalic acid supramolecular macrocycle, and this well-defined heterocluster forces, in its turn, DBA1 to form a van der Waals stabilized honeycomb lattice, leading to a three-component 2D crystal containing nine molecules in the unit cell. The recognition and selection events enable efficient error correction and healing in redundant mixtures. ; Publié en ligne le 16 juillet 2008 ; info:eu-repo/semantics/published