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Institute of Electrical and Electronics Engineers, IEEE Transactions on Magnetics, 6(46), p. 1382-1384, 2010

DOI: 10.1109/tmag.2010.2044480

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Defects Inducing Ferromagnetism in Carbon-Doped ZnO Films

Journal article published in 2010 by Xiao-Li Li, Jun-Feng Guo, Zhi-Yong Quan, Xiao-Hong Xu, Gillian A. Gehring
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Carbon-doped ZnO films were prepared on c-cut sapphire substrates by conventional PLD method. All films exhibit RT ferromagnetism. However, the samples deposited at low temperature and low pressure with low C concentration show large M s. The substitution of carbon for O in ZnO causes the electron transfer of 3d orbital of Zn ion, which results in the generation of a net spin with one half in the d-orbit of Zn, and accordingly makes ferromagnetism possible. XPS and Auger results indicate the formation of donor defects such as VO or/and Zni in the film, which makes the net spin align, accordingly induces magnetic ordering of the films. Both a certain number of donor defects and the net spin of Zn ions caused by the substitution of O by C are two key factors in inducing magnetic ordering in C-doped ZnO films. Therefore, defect-induced ferromagnetism is reasonable to explain the observed magnetism in our experiment.