Published in
Royal Society of Chemistry, Chemical Science, 26(14), p. 7126-7135, 2023
DOI: 10.1039/d3sc01235b
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Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions
Journal article published in 2023 by
Yuan Zhang,
Benjamin Ourri 
,
Pierre-Thomas Skowron,
Emeric Jeamet,
Titouan Chetot,
Christian Duchamp,
Ana M. Belenguer ,
Nicolas Vanthuyne ,
Olivier Cala ,
Elise Dumont ,
Pradeep K. Mandal ,
Ivan Huc ,
Florent Perret,
Laurent Vial ,
Julien Leclaire
,
Pierre-Thomas Skowron,
Emeric Jeamet,
Titouan Chetot,
Christian Duchamp,
Ana M. Belenguer ,
Nicolas Vanthuyne ,
Olivier Cala ,
Elise Dumont ,
Pradeep K. Mandal ,
Ivan Huc ,
Florent Perret,
Laurent Vial ,
Julien Leclaire
This paper is made freely available by the publisher.
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Abstract
The transfer of stereo-electronic information from achiral building blocks and templates to chiral cyclophanes is rationalized and exploited to produce self-assembled macrocyclic species carrying up to 16 stereogenic elements.