Published in
Royal Society of Chemistry, Chemical Science, 48(14), p. 14271-14279, 2023
DOI: 10.1039/d3sc04410f
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O–H bond activation of β,γ-unsaturated oximes via hydrogen atom transfer (HAT) and photoredox dual catalysis
Journal article published in 2023 by
Liang Yi,
Chen Zhu 
,
Xiangyu Chen ,
Huifeng Yue,
Tengfei Ji,
Yiqiao Ma ,
Yuanyuan Cao,
Rajesh Kancherla ,
Magnus Rueping
,
Xiangyu Chen ,
Huifeng Yue,
Tengfei Ji,
Yiqiao Ma ,
Yuanyuan Cao,
Rajesh Kancherla ,
Magnus Rueping
This paper is made freely available by the publisher.
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Abstract
Activating O–H bonds in β,γ-unsaturated oximes is challenging due to high redox potential. Our method combines HAT and photoredox catalysis to allow the synthesis of diverse heterocycles using various radical acceptors. Mechanistic studies support the HAT process in O–H bond activation.