Optical skyrmions are quasiparticles with nontrivial topological textures that have significant potential in optical information processing, transmission, and storage. Here, we theoretically and experimentally achieve the conversion of optical skyrmions among Néel, Bloch, intermediate skyrmions, and bimerons by polarization devices, where the fusion and annihilation of optical skyrmions are demonstrated accordingly. By analyzing the polarization pattern in Poincaré beams, we reveal the skyrmion topology dependence on the device, which provides a pathway for the study of skyrmion interactions. A vectorial optical field generator is implemented to realize the conversion and superposition experimentally, and the results are in good agreement with the theoretical predictions. These results enhance our comprehension of optical topological quasiparticles, which could have a significant impact on the transfer, storage, and communication of optical information.