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Royal Society of Chemistry, Chemical Science, 26(14), p. 7147-7153, 2023
DOI: 10.1039/d3sc01498c
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Catalytic asymmetric defluorinative allylation of silyl enol ethers
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Abstract
The exploitation of an intermolecular Si–F interaction between the substrates, together with chiral Lewis-base catalysis, allows the regio-, diastereo- and enantioselective allylation of ketone-derived silyl enol ethers with allyl fluorides.