AbstractThe features of electron pitch angle distributions (PADs) often imply different physical mechanisms in planetary magnetospheres. We report a simultaneous equatorial electrostatic electron cyclotron harmonic (ECH) wave event with butterfly PADs of electrons at L ∼ 7.6–9 observed by the Cassini spacecraft. Via calculating the bounce‐averaged electron diffusion rates, we found that Saturnian ECH waves can resonate with ∼10 eV to several keV electrons at <60° pitch angles at time scales from ∼10⁻⁸ to 10⁻⁴ s⁻¹. Simulations show that the formation of ∼100 eV to ∼1 keV electron butterfly PADs are mainly caused by the pitch angle scattering of electrons at low pitch angles (<30°) and the momentum scattering at intermediate pitch angles of ∼30°–45°, though previous studies suggested the adiabatic transport is the dominated mechanism. Additionally, our results successfully reproduce the variation of peak pitch angles (α_p) and phase space density ratios between α_90° and α_p with L‐shell.