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Royal Society of Chemistry, Chemical Science, 44(14), p. 12715-12722, 2023

DOI: 10.1039/d3sc03184e

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Photoinduced asymmetric charge trapping in a symmetric tetraazapyrene-fused bis(tetrathiafulvalene) conjugate

Journal article published in 2023 by Ping Zhou, Maryam Nazari Haghighi Pashaki, Hans-Martin Frey, Andreas Hauser, Silvio Decurtins, Andrea Cannizzo ORCID, Thomas Feurer, Robert Häner ORCID, Ulrich Aschauer ORCID, Shi-Xia Liu ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Asymmetric charge trapping in a symmetric TTF–TAP–TTF leads to a significant stabilization of the charge-separated state of a few ns, which contrasts strongly with the asymmetric TAP–TTF where rapid charge recombination occurs within 2 ps.