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Published in

American Institute of Physics, Physics of Fluids, 12(35), 2023

DOI: 10.1063/5.0174323

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Unveiling the non-equilibrium process in multilayer mixture adsorption

Journal article published in 2023 by Hsin-Chen Yu ORCID, Xiaoping Zhang ORCID, Nailiang Cao, Ruifeng Kan, Yi Xu ORCID, Zhongzhou Ren
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The Brunauer–Emmett–Teller (BET) theory [S. Brunauer et al., “Adsorption of gases in multimolecular layers,” J. Am. Chem. Soc. 60, 309–319 (1938)] constitutes a cornerstone in gas-adsorption physics. Recently, the kinetic BET equation of single-kind adsorbate has been proposed [H. Yu and X. Zhang, “Molecular-kinetic study of multilayers gas-adsorption in a rarefied gas environment,” Phys. Fluids 34, 123106 (2022)], while its counterpart of mixed adsorbates is currently unknown. Gas mixtures are commonly found in both natural and artificial systems. To address this limitation, we have proposed a kinetic BET theory for adsorbate mixtures in this paper. Moreover, we gave an analytical solution addressing low gas pressure conditions. In this condition, we predicted the “over-adsorption” of one species in the mixture with a higher desorption rate over time, and the “inertia effect” during the crowed-out process of the fast-desorbing species. Further, we also simulated the reciprocal influence of multilayer gas adsorption on the non-equilibrium fluids. Our findings provide valuable insights into gas-adsorption experiments and can facilitate technological advancements.