AbstractNanoplatelets (NPLs) share excellent luminescent properties with their symmetric quantum dots counterparts and entail special characters benefiting from the shape, like the thickness‐dependent bandgap and anisotropic luminescence. However, perovskite NPLs, especially those based on iodide, suffer from poor spectral and phase stability. Here, stable CsPbI₃ NPLs obtained by accelerating the crystallization process in ambient‐condition synthesis are reported. By this kinetic control, the rectangular NPLs into quasi‐square NPLs are tuned, where enlarged width endows the NPLs with a lower surface‐area‐to‐volume ratio (S/V ratio), leading to lower surficial energy and thus improved endurance against NPL fusion (cause for spectral shift or phase transformation). The accelerated crystallization, denoting the fast nucleation and short period of growth in this report, is enabled by preparing a precursor with complete transformation of PbI₂ into intermediates (PbI₃⁻), through an additional iodide supplier (e.g., zinc iodide). The excellent color stability of the materials remains in the light‐emitting diodes under various bias stresses.