Published in
Royal Society of Chemistry, Chemical Science, 1(15), p. 146-153, 2024
DOI: 10.1039/d3sc04955h
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Exploring the local solvation structure of redox molecules in a mixed solvent for increasing the Seebeck coefficient of thermocells
Journal article published in 2024 by
Hirotaka Inoue,
Hongyao Zhou 
,
Hideo Ando ,
Sakuya Nakagawa,
Teppei Yamada
,
Hideo Ando ,
Sakuya Nakagawa,
Teppei Yamada
This paper is made freely available by the publisher.
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Abstract
One-electron oxidation of a chloranil dianion (CA2−) to its radical form (CA˙−) disrupts the local solvation structure formed by ethanol in acetonitrile, resulting in a large entropy change and a large Seebeck coefficient of CA2−/˙− thermocells.