Published in

American Geophysical Union, Geophysical Research Letters, 23(50), 2023

DOI: 10.1029/2023gl104354

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Ozone Fluxes Over a Boreal Lake Exhibit Enhanced Deposition at Nights

Journal article published in 2023 by P. L. Fung ORCID, Ü. Rannik ORCID, I. Mammarella ORCID, T. Vesala ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

AbstractA few studies on ozone deposition over lake water are available and so far only one using the eddy covariance technique (Wesely et al., 1981, https://doi.org/10.1007/BF00122295). A 23‐day field campaign was held in August‐September 2012 at the Lake Kuivajärvi in Hyytiälä, Finland. The results showed a mean flux of −30 ± 1 ng m−2 s−1 and deposition velocity of 0.86 ± 0.05 mm s−1. Deposition velocity showed a weak diurnal cycle over the lake with elevated values during the nighttime. The daytime and nighttime portions of the data set differed statistically. Analysis showed that waterside convective mixing enhanced deposition and such conditions pre‐dominantly occurred during nighttime. We compared the measured deposition velocities with the dry deposition model of air‐sea exchange, adjusted for the chemical sinks relevant for the lake. We suggest that the buoyant mixing and unaccounted chemistry can be responsible for the difference between the model results and observations.