Published in
Royal Society of Chemistry, Chemical Science, 37(14), p. 10129-10139, 2023
DOI: 10.1039/d3sc02806b
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Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
Journal article published in 2023 by
Catherine Ellen Johnson 
,
Jesper Schwarz ,
Mawuli Deegbey ,
Om Prakash,
Kumkum Sharma,
Ping Huang ,
Tore Ericsson,
Lennart Häggström,
Jesper Bendix,
Arvind Kumar Gupta ,
Elena Jakubikova ,
Kenneth Wärnmark ,
Reiner Lomoth
,
Jesper Schwarz ,
Mawuli Deegbey ,
Om Prakash,
Kumkum Sharma,
Ping Huang ,
Tore Ericsson,
Lennart Häggström,
Jesper Bendix,
Arvind Kumar Gupta ,
Elena Jakubikova ,
Kenneth Wärnmark ,
Reiner Lomoth
This paper is made freely available by the publisher.
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Abstract
Photoluminescence of the FeIII complex occurs only from its 2LMCT state while its higher-energy but shorter-lived 2MLCT state is non-luminescent. Blue emission arises instead from a photoproduct of the non-emitting FeII complex.