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Royal Society of Chemistry, Chemical Science, 19(14), p. 5188-5195, 2023

DOI: 10.1039/d3sc01487h

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Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation

Journal article published in 2023 by K. Yuvaraj ORCID, Jeremy C. Mullins, Thayalan Rajeshkumar, Iskander Douair ORCID, Laurent Maron ORCID, Cameron Jones ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The reductive tetramerisation of CO by Lewis base activated dimagnesium(i) compounds, in the presence of Mo(CO)6, led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).