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Published in

Structural Dynamics with X-ray and Electron Scattering, p. 85-125, 2023

DOI: 10.1039/bk9781837671564-00085

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Theory of Time-dependent Scattering

Book chapter published in 2023 by M. Simmermacher ORCID, P. M. Weber, A. Kirrander
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The theory for ultrafast X-ray and electron scattering is presented in a unified form, derived using time-dependent perturbation theory, and applied specifically to molecules in the gas phase. The components of the scattering signal (elastic, inelastic, and coherent mixed) are identified and their physical origins are discussed. A brief overview of the calculation of scattering matrix elements, which are required for both analyses and simulations of scattering experiments, is given. Finally, a framework that accounts for rotational averaging as well as alignment due to single-photon excitation in the weak-field limit is provided.