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Royal Society of Chemistry, Chemical Science, 18(15), p. 6867-6873, 2024

DOI: 10.1039/d3sc06304f

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Shining light on tryptamine-derived isocyanides: access to constrained spirocylic scaffolds

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Tryptamine-derived isocyanides form aggregates at higher concentration that can form a charge transfer complex under visible light irradiation thus enabling a crucial single electron transfer step to generate carbon-based-radical intermediates.