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Royal Society of Chemistry, Chemical Science, 35(14), p. 9409-9417, 2023

DOI: 10.1039/d3sc03553k

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Studying manganese carbonyl photochemistry in a permanently porous metal–organic framework

Journal article published in 2023 by Rosemary J. Young ORCID, Michael T. Huxley, Lingjun Wu, Jack Hart ORCID, James O'Shea, Christian J. Doonan ORCID, Neil R. Champness ORCID, Christopher J. Sumby ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Photo-liberation of CO from a Mn(diimine)(CO)3Br moiety anchored within a permanently porous MOF support is studied. The crystallinity and structural flexibility of the MOF allows crystallographic snapshots of the photolysis products to be obtained.