ABSTRACT Young α-rich (YAR) stars within the old Galactic thick disc exhibit a dual characteristic of relative youth determined with asteroseismology and abundance enhancement in α elements measured from high-resolution spectroscopy. The youth origin of YAR stars has been proposed to be binary evolution via mass transfer or stellar mergers. If that is the case, YAR stars should spin rapidly and thus be magnetically active, because they are mass and angular momentum gainers. In this study, to seek this binary footprint, we select YAR stars on the main-sequence turn-off or the subgiant branch (MSTO-SGB) from APOGEE DR17, whose ages and projected rotation velocities (vsin i) can be precisely measured. With APOGEE vsin i and LAMOST spectra, we find that YAR stars are indeed fast rotators and magnetically active. In addition, we observe low [C/N] ratios and high Gaia RUWE in some YAR stars, suggesting that these MSTO-SGB stars probably have experienced mass transfer from red-giant companions. Our findings underscore that magnetic activity can serve as a valuable tool for probing the binary evolution for other chemically peculiar stars, such as red giants with lithium anomalies and carbon-enhanced metal-poor stars.