Published in
Royal Society of Chemistry, Chemical Science, 37(14), p. 10219-10235, 2023
DOI: 10.1039/d3sc03428c
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Photochemical charge accumulation in a heteroleptic copper(i)-anthraquinone molecular dyad via proton-coupled electron transfer
Journal article published in 2023 by
Zhu-Lin Xie 
,
Nikita Gupta ,
Jens Niklas ,
Oleg G. Poluektov ,
Vincent M. Lynch,
Ksenija D. Glusac,
Karen L. Mulfort
,
Nikita Gupta ,
Jens Niklas ,
Oleg G. Poluektov ,
Vincent M. Lynch,
Ksenija D. Glusac,
Karen L. Mulfort
This paper is made freely available by the publisher.
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Abstract
An earth-abundant Cu(i) chromophore-anthraquinone dyad is reported to photochemically accumulate two electrons at the anthraquinone via proton-coupled electron transfer, generating the monoprotonated photoproduct.