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Wiley, European Journal of Organic Chemistry, 22(26), 2023

DOI: 10.1002/ejoc.202300125

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Visible‐Light‐Induced Insertion of Sulfur Dioxide Mediated by Electron Donor–Acceptor Complex: Synthesis and Photophysical Properties of 3‐Sulfonyl Indolizines

Journal article published in 2023 by Delphine Naud‐Martin, Marharyta Kosiuha, Leandro H. Zucolotto Cocca ORCID, Pascal Retailleau, Florence Mahuteau‐Betzer ORCID, Leonardo De Boni ORCID, Sandrine Piguel ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

AbstractThis work investigates a light‐driven 3‐component sulfonylation reaction of indolizines without needing any external photocatalyst. The mechanistic investigations support the formation of an electron donor–acceptor (EDA) complex in situ. This transformation offers a mild and sustainable approach with high functional group tolerance for the synthesis of 3‐sulfonylated indolizines. This compound class has valuable photophysical properties and represents promising candidates in various applications related to fluorescence.