AbstractA spin-1/2 Heisenberg antiferromagnetic chain is one of the most important paradigmatic models in quantum magnetism. Its ground state is a spin singlet, while the excitation spectrum is formed by gapless fractional excitations, spinons. The presence of alternating g-tensors and/or the staggered Dzyaloshinskii-Moriya interaction results in opening the energy gap $\varDelta ∝ H^{2/3}$ Δ ∝ H 2 / 3 , once the magnetic field H is applied. A fairly good understanding of this phenomenon was achieved in the framework of the sine-Gordon quantum-field theory, taking into account the effective transverse staggered field induced by the applied uniform field. The theory predicts solitons and antisolitons as elementary excitations, as well as their bound states, breathers. Here, I review recent high-field electron spin resonance spectroscopy studies of such systems, focusing on peculiarities of their spin dynamics in the sine-Gordon regime and beyond.