AbstractIn this work, we demonstrate two types of heterogeneous irradiated-pristine polyethylene nanofiber junctions, ‘heavily-irradiated-pristine’ (HI-P) and ‘lightly-irradiated-pristine’ (LI-P) junctions, as high-performance solid-state thermal diodes. The HI-P junction rectifies heat flux in a single direction, while the LI-P junction shows dual-directional rectification under different working temperatures. We accurately model the phase transition of polyethylene nanofibers with a finite temperature range rather than a step function. The finite-temperature-range model suggests that the rectification factor increases with temperature bias and there is a minimum threshold of temperature bias for notable rectification. Besides, the finite-temperature-range model shows better prediction for the heat flow data from experiments, while the step function model tends to overestimate the rectification performance around the optimal length fraction of irradiation. Although both the models show that an optimal rectification occurs when the interface temperatures in the forward and the reverse biases are equal, the optimized rectification factor is determined by the temperature bias and the temperature range of phase transition. This work elucidates the influence of both the temperature bias and the temperature range of phase transition on thermal rectification performance, which could incredibly benefit the evaluation and design of thermal diodes.