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Royal Society of Chemistry, Chemical Science, 20(12), p. 6983-6991, 2021

DOI: 10.1039/d1sc00987g

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Design of pure heterodinuclear lanthanoid cryptate complexes

Journal article published in 2021 by Christian Dirk Buch ORCID, Steen H. Hansen, Dmitri Mitcov ORCID, Camilla Mia Tram, Gary S. Nichol ORCID, Euan K. Brechin ORCID, Stergios Piligkos ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We present a synthetic strategy to prepare the first heterodinuclear lanthanide(iii) cryptate complexes. The cryptate design ensures that the complexes are stable in solution for days. The exchange coupling in YbYb, GdGd and YbGd is investigated.