A new 4D memristive chaotic system with an infinite number of equilibria is proposed via exhaustive computer search. Interestingly, such a new memristive system has a plane of equilibria and two other lines of equilibria. Lyapunov exponent and bifurcation analysis show that this system has chaotic solutions with coexisting attractors. The basins of attraction of the coexisting attractors show chaos, stable fixed-points, and unbounded solutions. Furthermore, the 2D parameter space of the system is explored to find the optimum values of the parameters using the ALO (Ant Lion Optimizer) optimization algorithm.