Dissemin is shutting down on January 1st, 2025

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Royal Society of Chemistry, Chemical Science, 32(12), p. 10732-10741, 2021

DOI: 10.1039/d1sc02551a

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Non-metal with metal behavior: metal-free coordination-insertion ring-opening polymerization

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The first metal-free “coordination-insertion” ROP of cyclic carbonate and lactones mediated by N-trimethylsilyl-bis(trifluoromethanesulfonyl)imide (TMSNTf2) was proposed, which in the past was exclusively the monopoly of metal complex catalysts.