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Wiley, Advanced Materials, 33(25), p. 4653-4656, 2013

DOI: 10.1002/adma.201301997

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A Dense Metal-Organic Framework for Enhanced Magnetic Refrigeration

Journal article published in 2013 by Giulia Lorusso ORCID, Joseph W. Sharples, Elias Palacios, Olivier Roubeau ORCID, Euan K. Brechin ORCID, Roberta Sessoli ORCID, Andrea Rossin, Floriana Tuna, Eric J. L. McInnes, David Collison, Marco Evangelisti, J. W. Sharples E Palacios O Roubeau E K. Brechin R Sessoli A Rossin F Tuna E J. L. McInnes D Collison M Evangelisti G. Lorusso
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The three-dimensional metal-organic framework Gd(HCOO)3 is characterized by a relatively compact crystal lattice of weakly interacting Gd(3+) spin centers interconnected via lightweight formate ligands, overall providing a remarkably large magnetic:non-magnetic elemental weight ratio. The resulting magnetocaloric effect per unit volume is decidedly superior in Gd(HCOO)3 than in the best known magnetic refrigerant materials for liquid-helium temperatures and low-moderate applied fields.