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International Union of Geological Sciences, Episodes, 4(32), p. 249-263, 2009

DOI: 10.18814/epiiugs/2009/v32i4/002

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Understanding gold-(silver)-telluride-(selenide) mineral deposits

This paper is available in a repository.
This paper is available in a repository.

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Abstract

as part of the epithermal deposit spectrum in his textbook "Mineral deposits". Telluride-enrichment is, however, observed in a far wider range of deposit types, e.g., Au-rich VMS deposits, porphyry Au(Cu) and Au skarns. In at least some of these, a proportion of the gold occurs as Au-(Ag)-tellurides, or as native gold/Au-minerals paragenetically tied with tellurides of other elements, notably bismuth. Despite their enrichment in Te, gold deposits formed under reducing conditions are generally not acknowledged as Au-telluride deposits, because the telluride-rich character is largely expressed through an abundance of Bi-telluride species, commonly stable together with native bismuth. Gold-Bi compounds, such as maldonite and/or jonassonite, contribute to the mineralogical balance of gold ore, instead of Au(Ag)-tellurides (Ciobanu et al., 2005). A modified definition of the term 'gold-telluride deposits' was thus proposed (Cook and Ciobanu, 2005) to encompass the genetic connotation given by the presence of tellurides other than those of Au-Ag. In a preface to a special issue of Mineralogy and Petrology, Ciobanu et al. (2006a) posed a series of questions concerning the 'how?' and 'why?' of gold-telluride deposit formation. They questioned some of the established thinking about how these deposits were understood, not because the ideas are wrong (on the contrary!), but to encourage debate, and look beyond the confines of what was known and which fitted well to certain epithermal deposits. Likewise, Cook and Ciobanu (2005) attempted to build a framework for the role of other types of hydrothermal systems in the generation of telluride-bearing deposits, raising certain taboos about classification, alternative settings and deposition mechanisms, the role of tellurides in orogenic gold systems and skarns, and what studies of trace mineralogy could contribute to the broader ore genesis perspective? They stressed the need to expand thermodynamic databases and modelling of ore-forming systems (Afifi et al., 1988; Zhang and Spry, 1994a; Simon et al., 1997) to cover a broader range of formation conditions, e.g., pH/eH variation vs. activity/fugacity of various aqueous/gas species in a hydrothermal system. Within a given deposit, telluride-rich ores can be precipitated either at the same site or separately from native gold ore, depending upon precipitation mechanisms and local setting. Contemporary perspectives (e.g., Cooke and McPhail, 2001) include a Te-rich source, generally magmatically-derived, transport of Te as aqueous/vapour species within hydrothermal fluid, and precipitation of Au-Ag-tellurides due to multi-stage boiling. In an epithermal-porphyry environment (<5 km), these vapours are transported at the upper part of the veins forming a low-grade Au-Te cap on top of the main Au mineralisation underneath. Whereas this model fits some telluride-bearing Au deposits (e.g., Gold-(silver)-telluride (selenide) ores occur as epithermal orogenic and intrusion related deposits. Although Te and Se are chalcophile elements and share geochemical affinity with Au, formation of selenides and other elements Ag-Au require acidic or reducing environments. The thermodynamic stability conditions for Au and Ag-tellurides and native tellurium indicate an epithermal environment. Analysis of mineral paragenensis, textures and compositional variation in tellurides/selenides suggest petrogenetic processes involving interaction with fluids leading to Au scavenging and entrapment in tellurides, changes in chemistry/rates of fluid infiltration and attaining equilibrium in a given assemblage.