Published in
Royal Society of Chemistry, Chemical Science, 42(12), p. 14224-14229, 2021
DOI: 10.1039/d1sc04180k
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Silacyclization through palladium-catalyzed intermolecular silicon-based C(sp<sup>2</sup>)–C(sp<sup>3</sup>) cross-coupling
Journal article published in 2021 by
Ying Qin,
Lianghui Li 
,
Jin-Yuan Liang,
Kailong Li,
Dongbing Zhao
,
Jin-Yuan Liang,
Kailong Li,
Dongbing Zhao
This paper is made freely available by the publisher.
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Abstract
Herein, we develop the first silacyclization between 2-halophenols and SCBs, which allows the modular assembly of sila-benzo[b]oxepines with good functional group tolerance and can be applied for the late-stage modification of biologically active molecules.