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Nature Research, npj Quantum Materials, 1(6), 2021

DOI: 10.1038/s41535-021-00387-6

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Ferromagnetism out of charge fluctuation of strongly correlated electrons in κ-(BEDT-TTF)2Hg(SCN)2Br

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

AbstractWe perform magnetic susceptibility and magnetic torque measurements on the organic κ-(BEDT-TTF)2Hg(SCN)2Br, which is recently suggested to host an exotic quantum dipole-liquid in its low-temperature insulating phase. Below the metal-insulator (MI) transition temperature, the magnetic susceptibility follows a Curie–Weiss law with a positive Curie–Weiss temperature, and a particular $M∝ \sqrt{H}$ M ∝ H curve is observed. The emergent ferromagnetically interacting spins amount to about 1/6 of the full spin moment of localized charges. Taking account of the possible inhomogeneous quasi-charge-order that forms a dipole-liquid, we construct a model of antiferromagnetically interacting spin chains in two adjacent charge-ordered domains, which are coupled via fluctuating charges on a Mott-dimer at the boundary. We find that the charge fluctuations can draw a weak ferromagnetic moment out of the spin singlet domains.