Published in
Royal Society of Chemistry, RSC Chemical Biology, 2(3), p. 227-230, 2022
DOI: 10.1039/d1cb00160d
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Trapping and structural characterisation of a covalent intermediate in vitamin B<sub>6</sub> biosynthesis catalysed by the Pdx1 PLP synthase
Journal article published in 2022 by
Matthew J. Rodrigues 
,
Nitai Giri ,
Antoine Royant,
Yang Zhang,
Rachel Bolton,
Gwyndaf Evans,
Steve E. Ealick ,
Tadhg Begley,
Ivo Tews
,
Nitai Giri ,
Antoine Royant,
Yang Zhang,
Rachel Bolton,
Gwyndaf Evans,
Steve E. Ealick ,
Tadhg Begley,
Ivo Tews
This paper is made freely available by the publisher.
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Abstract
Explaining stereoselective deprotonation and phosphate elimination in PLP biosynthesis through crystal structure, UV-vis absorption spectroscopic and mass spectrometric characterisation of a chromophoric intermediate.