Published in

Royal Society of Chemistry, Chemical Science, 47(12), p. 15603-15608, 2021

DOI: 10.1039/d1sc05135k

Links

Tools

Export citation

Search in Google Scholar

Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction

Journal article published in 2021 by Takumi Oishi, Leonardo I. Lugo-Fuentes, Yichuan Jing, J. Oscar C. Jimenez-Halla, Joaquín Barroso-Flores ORCID, Masaaki Nakamoto, Yohsuke Yamamoto ORCID, Nao Tsunoji ORCID, Rong Shang ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Red circle
Preprint: archiving forbidden
Green circle
Postprint: archiving allowed
Upload
Green circle
Published version: archiving allowed
Upload
Policy details
Data provided by SHERPA/RoMEO

Abstract

A (bisborane)triarylphosphine was developed to spontaneously generate H2 from water under ambient conditions, revealing an unprecedented multi-centered electron relay mechanism for a metal-free umpolung of proton to hydride.