AbstractMetal halide perovskite photodiodes (PPDs) offer high responsivity and broad spectral sensitivity, making them attractive for low-cost visible and near-infrared sensing. A significant challenge in achieving high detectivity in PPDs is lowering the dark current density (J_D) and noise current (i_n). This is commonly accomplished using charge-blocking layers to reduce charge injection. By analyzing the temperature dependence of J_D for lead-tin based PPDs with different bandgaps and electron-blocking layers (EBL), we demonstrate that while EBLs eliminate electron injection, they facilitate undesired thermal charge generation at the EBL-perovskite interface. The interfacial energy offset between the EBL and the perovskite determines the magnitude and activation energy of J_D. By increasing this offset we realized a PPD with ultralow J_D and i_n of 5 × 10⁻⁸ mA cm⁻² and 2 × 10⁻¹⁴ A Hz^−1/2, respectively, and wavelength sensitivity up to 1050 nm, establishing a new design principle to maximize detectivity in perovskite photodiodes.