We put forward and demonstrate with model particles a smart laser-diffraction analysis technique aimed at particle mixture identification. We retrieve information about the size, shape, and ratio concentration of two-component heterogeneous model particle mixtures with an accuracy above 92%. We verify the method by detecting arrays of randomly located model particles with different shapes generated with a Digital Micromirror Device (DMD). In contrast to commonly-used laser diffraction schemes—In which a large number of detectors are needed—Our machine-learning-assisted protocol makes use of a single far-field diffraction pattern contained within a small angle (∼0.26°) around the light propagation axis. Therefore, it does not need to analyze particles of the array individually to obtain relevant information about the ensemble, it retrieves all information from the diffraction pattern generated by the whole array of particles, which simplifies considerably its implementation in comparison with alternative schemes. The method does not make use of any physical model of scattering to help in the particle characterization, which usually adds computational complexity to the identification process. Because of its reliability and ease of implementation, this work paves the way towards the development of novel smart identification technologies for sample classification and particle contamination monitoring in industrial manufacturing processes.