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Wiley, Angewandte Chemie International Edition, 48(52), p. 12692-12695, 2013

DOI: 10.1002/anie.201306263

Wiley, Angewandte Chemie, 48(125), p. 12924-12927, 2013

DOI: 10.1002/ange.201306263

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Hematite-Based Water Splitting with Low Turn-On Voltages

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Power up: The photoelectrochemical performance of hematite in a water-splitting device was improved significantly through surface modification with amorphous NiFeOx (see graph showing the large cathodic shift observed; FTO=fluorine-doped tin oxide). The measured photovoltage increased from 0.24 to 0.61 V, which yielded a record-low turn-on potential of 0.62 V (versus the reversible hydrogen electrode, RHE).