Published in
Royal Society of Chemistry, Chemical Science, 13(13), p. 3740-3747, 2022
DOI: 10.1039/d2sc00500j
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α-Branched amines through radical coupling with 2-azaallyl anions, redox active esters and alkenes
Journal article published in 2022 by
Shengzu Duan,
Yujin Zi,
Lingling Wang,
Jielun Cong,
Wen Chen 
,
Minyan Li,
Hongbin Zhang ,
Xiaodong Yang ,
Patrick J. Walsh
,
Minyan Li,
Hongbin Zhang ,
Xiaodong Yang ,
Patrick J. Walsh
This paper is made freely available by the publisher.
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Abstract
A mild method for the construction of α-branched amine derivatives is presented. SET processes between the Ni catalyst, redox active esters and 2-azaallyl anions generate azaallyl radicals and alkyl radicals that functionalize the alkenes.