Published in

Taylor and Francis Group, International Journal of Environmental Analytical Chemistry, 1-3(46), p. 163-174

DOI: 10.1080/03067319208027007

Links

Tools

Export citation

Search in Google Scholar

The nonreversibility of adsorption-desorption of dieldrin and lindane on chitin in seawater

Journal article published in 1992 by J. Perez-Peña, J. Magdalena Santana-Casiano ORCID, M. Gonzalez-Davila ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Red circle
Preprint: archiving forbidden
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Adsorption and desorption of dieldrin and lindane on chitin were investigated in seawater batch tests as a function of chitin concentration, temperature, pH and salinity. For chitin concentrations ranging from 0.5 g l to 12.5 g l, the pesticide concentrations were varied from 4 μgl to 65 μg for dieldrin and from 40 μl to 680 μg l for lindane. Both dieldrin and lindane show adsorption-desorption hysteresis at low chitin concentration. At high chitin concentrations (m > 6.25 g l for dieldrin and m > 10 gl for lindane) both pesticides exhibit reversible behaviour. However, only lindane adsorption is affected by chitin concentration. These types of behaviour remain fixed in prewashed chitin. However, an increase in the temperature and a decrease in the salinity made the process become reversible. A resistant-reversible two component model has been applied to account for these types of behaviour and provides a way to explain most of the observed effects by defining mass independent distribution coefficients.