Published in

Taylor and Francis Group, Journal of Coordination Chemistry, 1(54), p. 13-24, 2001

DOI: 10.1080/00958970108022626

Links

Tools

Export citation

Search in Google Scholar

An unusual ruthenium(II) complex of 2-(2-pyridyl)benzothiazole

Journal article published in 2001 by Milan Maji, Parbati Sengupta, Shyamal Kumar Chattopadhyay ORCID, Golam Mostafa, C. H. Schwalbe, Saktiprosad Ghosh
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Red circle
Preprint: archiving forbidden
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The ligand 2-(2-pyridyl)benzothiazole (L) can act both as an N-N and an N-S chelating donor. The latter coordination mode is expected to be preferred when it is involved in coordination to Ru(II) which is a soft acceptor centre However, in the title compound, chlorobis(acetonitrile)triphenylphosphino-2-(2-pyridyl)benzothiazole-N,N-ruthenium(II) chlride, [Ru(L)(PPh3(CH3CN)2Cl]Cl, the ligand acts in N,N-bidentate manner and the Ru(II) ion is found to be present in an N4PCl coordination environment. PPh3 and Cl are trans to each other and the two CH3CN ligands occupy cis positions facing the NN donor atoms of ligand L.