Increasing demand for sustainable approaches to mining and raw material extraction, has prompted the need to explore advanced methods of surface modification for structural steels used in the extractive industry. The technology of powder plasma transferred arc welding (PPTAW), was used in this study as a surface modification technique to improve upon the abrasive wear resistance of structural steel grade EN S355. PPTAW process parameters, namely, plasma transferred arc (PTA) current and plasma gas flow rate (PGFR), were varied, and the effects of the variation were studied and used as criteria for selecting optimum conditions for further studies and parametric reproducibility. Two metal matrix composite (MMC) powders were used in the process, having compositions of Ni-Si-B+60 wt%WC (PG) and Ni-Cr-Si-B+45 wt%WC (PE). Microstructural observation under a scanning electron microscope (SEM) revealed a dendritic, multi-directional microstructure consisting of partially dissolved primary tungsten carbide particles and secondary tungsten carbide precipitates within the MMC solid solution. The hardness of the surface layers was higher than that of a reference AR400 steel by more than 263 HV. Final surface layers obtained from the MMC powders had abrasive wear resistance up to 5.7 times that of abrasion-resistant reference AR400 steel. Alloying the MMC matrix with chromium increased the hardness by 29.4%. Under the same process conditions, MMC powder with 60 wt% WC reinforcement had better abrasive wear resistance by up to 45.8% more than the MMC powder with 45 wt% WC.