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arXiv, 2022

DOI: 10.48550/arxiv.2202.02227

American Physical Society, Physical Review B, 9(106), 2022

DOI: 10.1103/physrevb.106.094510

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Evolution of lattice, spin, and charge properties across the phase diagram of FeSe1−xSx

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A Raman scattering study covering the entire substitution range of the FeSe$_{1-x}$S$_x$ solid solution is presented. Data were taken as a function of sulfur concentration $x$ for $0\le x \le 1$, of temperature and of scattering symmetry. All type of excitations including phonons, spins and charges are analyzed in detail. It is observed that the energy and width of iron-related B$_{1g}$ phonon mode vary continuously across the entire range of sulfur substitution. The A$_{1g}$ chalcogenide mode disappears above $x=0.23$ and reappears at a much higher energy for $x=0.69$. In a similar way the spectral features appearing at finite doping in A$_{1g}$ symmetry vary discontinuously. The magnetic excitation centered at approximately 500 cm$^{-1}$ disappears above $x=0.23$ where the A$_{1g}$ lattice excitations exhibit a discontinuous change in energy. The low-energy mode associated with fluctuations displays maximal intensity at the nemato-structural transition and thus tracks the phase boundary.