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American Chemical Society, Journal of the American Chemical Society, 40(136), p. 13991-13994, 2014

DOI: 10.1021/ja507799e

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1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion

Journal article published in 2014 by Hsueh-Ju Liu, Julie Guihaumé, Thomas Davin, Christophe Raynaud ORCID, Odile Eisenstein ORCID, T. Don Tilley
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

An intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.