Published in
Royal Society of Chemistry, Chemical Science, 42(13), p. 12550-12559, 2022
DOI: 10.1039/d2sc04339d
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Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation
Journal article published in 2022 by
Matthew R. Elsby 
,
Changjin Oh ,
Mina Son ,
Scott Y. H. Kim,
Mu-Hyun Baik ,
R. Tom Baker
,
Changjin Oh ,
Mina Son ,
Scott Y. H. Kim,
Mu-Hyun Baik ,
R. Tom Baker
This paper is made freely available by the publisher.
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Abstract
The role of a phosphine-free SNS-pincer ligand in metal–ligand cooperative hydroboration catalysis was investigated. The bifunctional thiolate donor and spin-state change to high-spin Mn are crucial to accessing low-energy activation barriers.