Abstract Percolation, describing critical behaviors of phase transition in a geometrical context, prompts wide investigations in natural and social networks as a fundamental model. The introduction of quantum coherence and superposition brings percolation into quantum regime with more fascinating phenomena and unique features, which, however, has not been experimentally explored yet. Here we successfully map these large-scale porous structures into a photonic chip using femtosecond laser direct writing techniques and present an experimental demonstration of quantum transport in hexagonal percolation lattices, probed by coherent light. A quantum percolation threshold of 80% is observed in the prototyped laser-written lattices with up to 1,600 waveguides, which is significantly larger than the classical counterpart of 63%. We also investigate the spatial confinement by localization parameters and exhibit the transition from ballistic to diffusive propagation with the decrease of the occupation probability. Direct observation of quantum percolation may deepen the understanding of the relation among materials, quantum transport, geometric quenching, disorder and localization, and inspire applications for quantum technologies.