Interaction of multiple shocks plays a critical role in setting up an adiabatic compression of megabar pressure in nanosecond timescale in inertial confinement fusion. In this paper, we present observations of dynamic behavior and interaction of multiple shocks in polystyrene (CH) planar targets driven by a single-ramp pulse of 2.5 ns at the SG-II laser facility with a specially designed velocity interferometer system for any reflector (VISAR). A maximum pressure of [Formula: see text] and a mass density of [Formula: see text] are measured, respectively. Radiation-hydrodynamic simulations reveal the interaction process of the multiple shocks and are in good agreement with the measurements. A theoretical model is proposed to invert the space-time history of the shock generation with the VISAR data. Moreover, an optimized double-slope ramp pulse is proposed for further compression experiments. The improved multiple-shock coalescence is expected to effectively enhance both density and velocity for an initial compression of the CH target.